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Nematic liquid crystals exhibit nanosecond electro-optic response to an applied electric field which modifies the degree of orientational order without realigning the molecular orientation. However, this nanosecond electrically-modified order parameter (NEMOP) effect requires high driving fields, on the order of 108 V/m for a modest birefringence change of 0.01. In this work, we demonstrate that a nematic phase of the recently discovered ferroelectric nematic materials exhibits a robust and fast electro-optic response. Namely, a relatively weak field of 2×107 V/m changes the birefringence by ≈ 0.04 with field-on and -off times around 1 μs. This microsecond electrically modified order parameter (MEMOP) effect shows a greatly improved figure of merit when compared to other electro-optical switching modes in liquid crystals, including the conventional Frederiks effect, and has a potential for applications in fast electro-optical devices such as phase modulators, optical shutters, displays, and beam steerers. 

Nematic liquid crystals exhibit nanosecond electro-optic response to an applied electric field which modifies the degree of orientational order without realigning the molecular orientation. However, this nanosecond electrically modified order parameter (NEMOP) effect requires high driving fields, on the order of 10⁸V/m for a modest birefringence change of 0.01. In this work, we demonstrate that a nematic phase of the recently discovered ferroelectric nematic materials exhibits a robust and fast electro-optic response. Namely, a relatively weak field of 2 × 10⁷V/m changes the birefringence by ≈ 0.04 with field-on and-off times around 1 μs. This microsecond electrically modified order parameter (MEMOP) effect shows a greatly improved figure of merit when compared to other electro-optical switching modes in liquid crystals, including the conventional Frederiks effect, and has a potential for applications in fast electro-optical devices such as phase modulators, optical shutters, displays, and beam steerers. 

Six members of the 1,ω-bis(4-cyanobiphenyl-4′-yl) alkanes are reported and referred to as CBnCB in which n = 1, 15, 16, 17, 19 and 20 and indicates the number of methylene units in the spacer separating the two cyanobiphenyl units. The behaviour of CB3CB is revisited. The temperature dependence of the refractive indices, optical birefringence, and dielectric permittivities measured in the nematic, N, phase for selected homologues are reported. The dimers with n ≥ 15 showed an enantiotropic N phase, and for the odd members the twist-bend nematic, NTB, phase was observed. CB3CB shows a direct NTB-isotropic, I, transition whereas for CB1CB a virtual NTB-I transition is found. The temperature dependence of the bend elastic constant, K33, measured in the oblique helicoidal cholesteric state formed by mixtures of CBnCB with a chiral additive S811, shows strong non-monotonous behaviour with a deep minimum near the transition point to the NTB phase. The minimum value of K_33 decreases as n increases. The long even members of the CBnCB series show similar values of TNI to their odd-membered counterparts but their estimated values of TNTBN are considerably lower. This is attributed to molecular shape and its effect on K33. 

AbstractAn oblique helicoidal state of a cholesteric liquid crystal (Ch_OH) is capable of continuous change of the pitch$$P$$ $P$in response to an applied electric field. Such a structure reflects 50% of the unpolarized light incident along the Ch_OHaxis in the electrically tunable band determined by$$P$$ $P$/2. Here, we demonstrate that at an oblique incidence of light, Ch_OHreflects 100% of light of any polarization. This singlet band of total reflection is associated with the full pitch$$P$$ $P$. We also describe the satellite$$P/2$$ $P/2$,$$P/3$$ $P/3$, and$$P/4$$ $P/4$bands. The$$P/2$$ $P/2$and$$P/4$$ $P/4$bands are triplets, whereas$$P/3$$ $P/3$band is a singlet caused by multiple scatterings at$$P$$ $P$and$$P/2$$ $P/2$. A single Ch_OHcell acted upon by an electric field tunes all these bands in a very broad spectral range, from ultraviolet to infrared and beyond, thus representing a structural color device with enormous potential for optical and photonic applications. Impact statementPigments, inks, and dyes produce colors by partially consuming the energy of light. In contrast, structural colors caused by interference and diffraction of light scattered at submicrometer length scales do not involve energy losses, which explains their widespread in Nature and the interest of researchers to develop mimicking materials. The grand challenge is to produce materials in which the structural colors could be dynamically tuned. Among the oldest known materials producing structural colors are cholesteric liquid crystals. Light causes coloration by selective Bragg reflection at the periodic helicoidal structure formed by cholesteric molecules. The cholesteric pitch and thus the color can be altered by chemical composition or by temperature, but, unfortunately, dynamic tuning by electromagnetic field has been elusive. Here, we demonstrate that a cholesteric material in a new oblique helicoidal Ch_OHstate could produce total reflection of an obliquely incident light of any polarization. The material reflects 100% of light within a band that is continuously tunable by the electric field through the entire visible spectrum while preserving its maximum efficiency. Broad electric tunability of total reflection makes the Ch_OHmaterial suitable for applications in energy-saving smart windows, transparent displays, communications, lasers, multispectral imaging, and virtual and augmented reality. Graphical Abstract 

We explore the structures and confinement-induced edge dislocations in Grandjean-Cano wedge cells filled with the recently discovered chiral ferroelectric nematic (N_F^*) and chiral antiferroelectric smectic-Z 〖(SmZ〗_A^*). The chiral mixture is formed by DIO mesogen doped with a chiral additive. Wedge cells with parallel and antiparallel rubbing at the opposite plates show quantitatively different structures which is attributed to the polar in-plane anchoring of the spontaneous polarization at the rubbed substrates. The helical pitch shows a non-monotonous temperature dependence upon cooling, increasing as the temperature is lowered to the N^*-SmZ_A^* phase transition. The SmZ_A^* formed from an untwisted N^* in the thin portion of the wedge shows a bookshelf (BK) geometry, whereas the twisted N^* transforms into a twisted planar (PA) SmZ_A^* structure. In the N_F^* phase, the untwisted N^* becomes twisted in a wedge with antiparallel assembly of plates and monodomain in wedges with parallel assembly. The twisted regions of N_F^* show only one type of Grandjean zones separated by thick edge dislocations with Burgers vector b=P; the neighboring regions differ by 2π- twist. 

Abstract Surface interactions are responsible for many properties of condensed matter, ranging from crystal faceting to the kinetics of phase transitions. Usually, these interactions are polar along the normal to the interface and apolar within the interface. Here we demonstrate that polar in-plane surface interactions of a ferroelectric nematic N F produce polar monodomains in micron-thin planar cells and stripes of an alternating electric polarization, separated by $${180}^{{{{{{\rm{o}}}}}}}$$ 180 o domain walls, in thicker slabs. The surface polarity binds together pairs of these walls, yielding a total polarization rotation by $${360}^{{{{{{\rm{o}}}}}}}$$ 360 o . The polar contribution to the total surface anchoring strength is on the order of 10%. The domain walls involve splay, bend, and twist of the polarization. The structure suggests that the splay elastic constant is larger than the bend modulus. The $${360}^{{{{{{\rm{o}}}}}}}$$ 360 o pairs resemble domain walls in cosmology models with biased vacuums and ferromagnets in an external magnetic field.